A Convenient Synthesis of Methyl Jasmonate and γ-Jasmolactone
نویسندگان
چکیده
منابع مشابه
A convenient synthesis of γ-functionalized cyclopentenones
The synthesis of gamma-functionalized cyclopentenones was carried out in a few steps, starting firstly with the preparation of nitroketonic intermediates 2, which were readily transformed into 1,4-diketones using the Nef conversion. The intramolecular cyclization of the gamma-diketones 3 in a basic medium, led to the functionalized cyclopentenones 4.
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A series of amino acid methyl ester hydrochlorides were prepared in good to excellent yields by the room temperature reaction of amino acids with methanol in the presence of trimethylchlorosilane. This method is not only compatible with natural amino acids, but also with other aromatic and aliphatic amino acids.
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Some new macrocyclic dibenzotrioxadiamides, dibenzotetraoxadiamide, dibenzopentaoxadiamide, dibenzothiatrioxadiamide, tribenzotrioxadiamides and tetrabenzohexaoxadiamide (14-21), (26) and (27) have been prepared. These compounds were obtained in the macrocyclization step by reacting the diamine (4) with appropriak dicaxboxylic acid dichlorides (5-13) and (24). The cyclization does not requ...
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INTRODUCTION Jasmonoids have been found to play important roles in plant growth regulation.1 Recent development of industrial production of ()-methyl jasmonate (MJA, 1) from Nippon Zeon Co., Ltd. made it possible to use MJA as a practical plant growth regulator.2 we have been studying new jasmonoid analogs to develop more active compounds.3 we took notice of the hypothesis that the metabolic in...
متن کاملResponse of peppermint to methyl jasmonate application .
Jasmonate compounds are known as new plant hormones that play important roles in the regulation of plant growth and development. Mints have been used and valued as aromatic herbs for thousands of years. Peppermint (Mentha piperita L.) is used for medicinal and food purposes and its essential oil is considered industrially important. Peppermint plants were grown in a greenhouse in pots. At flowe...
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ژورنال
عنوان ژورنال: Journal of Japan Oil Chemists' Society
سال: 1984
ISSN: 1884-2003
DOI: 10.5650/jos1956.33.628